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Kofu Group

member
Professor KOFU, Maiko
Research Associate AKIBA, Hiroshi

Research Subjects

  • Dynamics of hydrogen atoms and hydrogen-containing molecules in a wide range of materials
  • Excitation characteristics of spin glasses
  • Spin dynamics of single-molecule magnets
  • Development of neutron scattering instruments and challenges to new measurements

We study the dynamics of atoms, molecules, and spins in various materials using neutron scattering techniques, to discover novel phenomena and universality inherent in a wide range of materials. Neutron is a powerful probe to detect hydrogen atoms. Observation of hydrogen quantum dynamics and proton/hydride ion conduction is one of our major research interests. Hydrogen is known as a quantum atom, but the quantum nature of hydrogen is rarely manifested. We will try new measurement techniques, such as coherent/incoherent separation of light hydrogen using polarized neutrons, and find dynamics that have not been captured so far. Hydrates, functional liquids, spin glass, and single-molecule magnets (which behave like nanomagnets) are also within our scope. These studies require measurements over a wide dynamic range, and we are using a variety of neutron spectrometers in domestic and foreign facilities, as well as developing a neutron scattering spectrometer.

Hydrogen state in palladium hydride nanoparticles studied by neutron diffraction, inelastic, and quasielastic scattering. Our comprehensive studies showed that some hydrogen atoms near the surface of the nanoparticles are accommodated at the tetrahedral sites, which is different from the bulk state, resulting in anharmonic vibrations and fast diffusion.
Bose-scaled localized magnetic excitation was commonly observed in various classical spin glasses. The excitation is highly reminiscent of localized vibrational modes (“boson peak”) in structural glasses. The broad spectrum with the high-energy tail can be attributed to elementary excitations in a multitude of metastable states.

Publications and Research Highlights