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Entropic elasticity and negative thermal expansion in a simple cubic crystal

Date : Thursday, November 28th, 2019 16:00 - 17:00 Place : Lecture Room (A632), 6th Floor, ISSP Lecturer : Prof. Igor Zaliznyak Affiliation : Brookhaven National Laboratory

While most solids expand when heated, some materials show the opposite behavior: negative thermal expansion (NTE). NTE is common in polymers and biomolecules, where it stems from the entropic elasticity of an ideal, freely-jointed chain. The origin of NTE in solids had been widely believed to be different, with phonon anharmonicity, and specific lattice vibrations that preserve geometry of the coordination polyhedra – rigid unit motions (RUMs) – as leading contenders for explaining NTE. Our neutron scattering study of a simple cubic NTE material, ScF3, overturns this consensus [1]. We observe that the correlation in the positions of the neighboring fluorine atoms rapidly fades on warming, indicating an uncorrelated thermal motion, which is only constrained by the rigid Sc-F bonds. These experimental findings lead us to a quantitative theory of NTE in terms of entropic elasticity of Coulomb floppy network crystal, which is applicable to a range of open framework ionic solids featuring floppy network architecture [2]. Our theory is in remarkable agreement with experimental results in ScF3, describing NTE, the phonon frequencies, the structural phase transition governed by entropic stabilization of criticality, and the entropic compressibility. We thus find that NTE in a family of insulating ceramic crystals stems from a simple and intuitive physics of entropic elasticity of an under-constrained floppy network, which has long been appreciated in soft matter and polymer science but has been broadly missed by the hard condensed matter community. Our results reveal the formidable universality of the NTE phenomenon across soft and hard matter [1,2].

[1] D. Wendt, et al., Sci. Adv. 5: eaay2748. (2019).
[2] A. V. Tkachenko, I. A. Zaliznyak. arXiv:1908.11643 (2019).

(Published on: Wednesday October 30th, 2019)